Bert, N. A., Chaldyshev, V. V., Musikhin, Y. G., Suvorova, A. A., Preobrazhenskii, V. V., Putyato, M. A., Semyagin, B. R. and Werner, P.
Applied Physics Letters 74, (10), pp 1442-1444 (1999) Low-temperature grown GaAs films with indium delta layers are studied by transmission electron microscopy. The delta layers in the as-grown film are found to be as thick as four monolayers (ML) independently of a nominal In deposit of 0.5 or 1 ML, a thickness which reflects the film surface roughness during the low-temperature growth. A pronounced In-Ga intermixing is observed in the films subjected to 500-700 degrees C isochronal anneals. The In-Ga interdiffusion diffusivity is evaluated. The effective activation energy for In-Ga interdiffusion is found to be 1.1 +/- 0.3 eV which is significantly smaller than a value of 1.93 eV for a stoichiometric GaAs. The difference seems to result from a loss of the gallium vacancy supersaturation upon annealing, and is consistent with an annihilation enthalpy of 0.8 eV. (C) 1999 American Institute of Physics. [S0003-6951(99)00310-1]. [References: 18]
Full text :PDF (396 kB)( for personal use only)